接枝聚合物的合成：聚丁二烯与苯乙烯、丙烯腈接枝是ABS生产工艺中的核心单元。粒径呈双峰分布的聚丁二烯胶乳连续送入乳液接枝反应器与苯乙烯和丙烯腈单体混合物进行接枝共聚反应。单体与聚丁二烯之比提高则接枝聚合物和SAN共聚物的分子量及接枝度增加，内部接枝率一般随橡胶粒径的增加和橡胶交联密度的降低而增加。在粒径和橡胶交联密度恒定时接枝度和接枝密度是决定ABS产品性能的因素。
SAN共聚物的合成：苯乙烯与丙烯晴共聚物合成方法有三种：乳液法、悬浮法和本体法。本体法采用热引发、连续聚合，产品纯净、质量较高，污染少，在SAN合成中正取代悬浮法，尤其在大型ABS生产装置上。悬浮法采用引发剂，间歇聚合、产品不如本体法纯净，产生的废水对环境有污染，但工艺简单，流程短，投资少，聚合热易撒出，对中小型装置而言悬浮法较为经济。乳液法流程长，技术落后，发达国家已基本淘汰。
特点：
综合性能较好,冲击强度较高,化学稳定性,电性能良好.
Our polycarbonate/acrylonitrile butadiene styrene materials (PC/ABS) combine the outstanding pureness and excellent processability of Trinseo's mass polymerization ABS resins with the superior impact and heat resistance of PC resins.
Trinseo's product families PULSE™ PC/ABS Resins and EMERGE™ Advanced Resins provide an industry-leading balance of attributes such as toughness (also at low temperatures), heat, ignition, and impact resistance that enable applications requiring enhanced physical properties and high aesthetic properties.
Our PC/ABS resins are available both pre-colored and as part of a self-coloring system. In close collaboration with our customers, the expert team in the Trinseo Coloring Group develops and implements solutions for all customer-specific coloring needs, whether for pre-colored material or to support the production of color masterbatches to supply together with our natural materials.
Worldwide, customers can benefit from supply security as a result of our compounding assets in each region (EU, NA, China). We offer our high levels of expertise and technical support along with our products around the world.
PC/ABS grades from our EMERGE™ Advanced Resins portfolio exhibit a special range of materials optimized to meet the complex needs of the consumer electronics, medical, electrical and lighting industries.
